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Carbon dioxide and hydrogen peroxide discovered on Charon

by | Oct 3, 2024 | Space Research and Exploration

A true colour image of Charon. Credit: NASA/ Johns Hopkins University Applied Physics Laboratory/ Southwest Research Institute/ Alex Parker, Public domain, via Wikimedia Commons.

Astronomers have discovered that the surface of Pluto’s moon Charon preserves materials from both formation and evolutionary processes.

A Southwest Research Institute-led team has detected carbon dioxide and hydrogen peroxide for the first time on the frozen surface of Pluto’s largest moon, Charon, using observations from the James Webb Space Telescope.

These discoveries add to Charon’s known chemical inventory, previously identified by ground- and space-based observations, that includes water ice, ammonia-bearing species and the organic materials responsible for Charon’s grey and red coloration.

Lead author SwRI’s Dr Silvia Protopapa, and co-investigator of the New Horizons mission, said: “Charon is the only mid-sized Kuiper Belt object, in the range of 300 to 1,000 miles in diameter, that has been geologically mapped, thanks to the SwRI-led New Horizons mission, which flew by the Pluto system in 2015.

“Unlike many of the larger objects in the Kuiper Belt, the surface of Charon is not obscured by highly volatile ices such as methane and therefore provides valuable insights into how processes like sunlight exposure and cratering affect these distant bodies.”

The Webb telescope is an ideal platform for detailed exploration of Charon and other icy bodies in the region beyond the orbit of Neptune.

In 2022 and 2023, the team used Webb’s Near-Infrared Spectrograph to obtain four observations of the Pluto-Charon system.

Different viewing geometries provided full coverage of Charon’s northern hemisphere.

​​​Co-author Dr Ian Wong, a staff scientist at the Space Telescope Science Institute, said: “The advanced observational capabilities of Webb enabled our team to explore the light scattered from Charon’s surface at longer wavelengths than what was previously possible, expanding our understanding of the complexity of this fascinating object.”

An SwRI-led team detected carbon dioxide and hydrogen peroxide spectral signatures on Pluto’s largest moon Charon using Webb telescope observations (white), which extend the wavelength coverage of previous New Horizons flyby measurements (pink). The JWST and New Horizons data are consistent in the spectral shape and the strength of the absorption bands at short wavelengths of light; the offset in the absolute amount of scattered light can largely be attributed to differences in viewing geometries. These findings offer clues about the formation and evolution of Charon, shown in the background as imaged by New Horizons. Credit: S Protopapa/ SwRI/ NASA/ ESA/ CSA/ STScI/ JHUAPL.

Signatures

The extended wavelength coverage of Charon’s Webb measurements reveals signatures of carbon dioxide.

The team compared the spectroscopic observations with laboratory measurements and detailed spectral models of the surface, concluding that carbon dioxide is present primarily as a surface veneer on a water ice-rich subsurface.

Protopapa said: “Our preferred interpretation is that the upper layer of carbon dioxide originates from the interior and has been exposed to the surface through cratering events.

“Carbon dioxide is known to be present in regions of the protoplanetary disk from which the Pluto system formed.”

The presence of hydrogen peroxide on the surface of Charon clearly indicates that the water ice-rich surface is altered by solar ultraviolet light and energetic particles from the solar wind and galactic cosmic rays.

Hydrogen peroxide forms from oxygen and hydrogen atoms originating from the breakup of water ice due to incoming ions, electrons or photons.

SwRI’s Dr Ujjwal Raut, leader of the Center for Laboratory Astrophysics and Space Science Experiments (CLASSE) lab and second author of the paper, added: “Laboratory experiments conducted at SwRI’s CLASSE facility were instrumental in demonstrating that hydrogen peroxide can form even in mixtures of carbon dioxide and water ice under conditions analogous to those at Charon.”

Unparalleled capability

The team’s research showcases the Webb telescope’s unparalleled capability to uncover complex surface signatures shaped by impacts and irradiation processes.

Protopapa concluded: “The new insights were made possible by the synergy between Webb observations, spectral modelling and laboratory experiments and are possibly applicable to other similar mid-sized objects beyond Neptune.”

The study is published in Nature Communications.

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